Nick Connor

A NaI(Tl) scintillation counter is a radiation detector which uses the effect known as scintillation. Scintillation, which occurs in the NaI(Tl) crystal, is a flash of light produced in a transparent material by the passage of a particle (an electron, an alpha particle, an ion, or a high-energy photon). Scintillation occurs in the scintillator, which is a key part of a scintillation detector. In general, a scintillation detector consists of:

• Scintillator. A scintillator generates photons in response to incident radiation.
• Photodetector. A sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal.

The basic principle of operation involves the radiation reacting with a scintillator, which produces a series of flashes of varying intensity. The intensity of the flashes is proportional to the energy of the radiation. This feature is very important. These counters are suited to measure the energy of  gamma radiation (gamma spectroscopy) and, therefore, can be used to identify gamma emitting isotopes.

Scintillation counters are widely used in radiation protection, assay of radioactive materials and physics research because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation. Hospitals all over the world have gamma cameras based on the scintillation effect and, therefore, they are also called scintillation cameras.

The advantages of a scintillation counter are its efficiency and the high precision and counting rates that are possible. These latter attributes are a consequence of the extremely short duration of the light flashes, from about 10^-9  (organic scintillators) to 10^-6 (inorganic scintillators) seconds. The intensity of the flashes and the amplitude of the output voltage pulse are proportional to the energy of the radiation. Therefore, scintillation counters can be used to determine the energy, as well as the number, of the exciting particles (or gamma photons). For gamma spectrometry, the most common detectors include sodium iodide (NaI) scintillation counters and high-purity germanium detectors.

Thallium-doped Sodium Iodide – NaI(Tl) scintillators

The most widely used scintillation material is NaI(Tl) (thallium-doped sodium iodide). NaI(Tl) as the scintillator is used in scintillation detectors, traditionally in nuclear medicine, geophysics, nuclear physics, and environmental measurements. The iodine provides most of the stopping power in sodium iodide (since it has a high Z = 53). These crystalline scintillators are characterized by high density, high atomic number, and pulse decay times of approximately 1 microsecond (~ 10^-6 sec). The wavelength of maximum emission is 415 nm. Scintillation in inorganic crystals is typically slower than in organic ones. They exhibit high efficiency for detection of gamma rays and are capable of handling high count rates. Inorganic crystals can be cut to small sizes and arranged in an array configuration so as to provide position sensitivity. This feature is widely used in medical imaging to detect X-rays or gamma rays. Inorganic scintillators are better at detecting gamma rays and X-rays. The NaI(Tl) scintillator has a higher energy resolution than a proportional counter, allowing for more accurate energy determinations. This is due to their high density and atomic number which gives a high electron density. A disadvantage of some inorganic crystals, e.g., NaI, is their hygroscopicity, a property which requires them to be housed in an airtight container to protect them from moisture. The crystals are usually coupled with a photomultiplier tube, in a hermetically sealed assembly.

Photomultiplier Tube

Photomultiplier tubes (PMTs) are a photon detection device that uses the photoelectric effect combined with secondary emission to convert light into an electrical signal. A photomultiplier absorbs light emitted by the scintillator and re-emit it in the form of electrons via the photoelectric effect. The PMT has been the main choice for photon detection ever since due to the fact that they have high quantum efficiency and high amplification.

Components of Photomultiplier Tube

The device consists of several components and these components are shown in the figure.

• Photocathode. Right after a thin entry window, is a photocathode, which is made of material in which the valence electrons are weakly bound and have a high cross section for converting photons to electrons via the photoelectric effect. For example, Cs₃Sb (caesium-antimony) may be used. As a result, the light created in the scintillator strikes the photocathode of a photomultiplier tube, releasing at most one photoelectron per photon.
• Dynodes. Using a voltage potential, this group of primary electrons is electrostatically accelerated and focused so that they strike the first dynode with enough energy to release additional electrons. There is a series (“stages”) of dynodes made of material of relatively low work function. These electrodes are operated at ever increasing potential (e.g. ~100-200 V between dynodes). At the dynode the electrons are multiplied by secondary emission. The next dynode has a higher voltage which makes the electrons released from the first to accelerate towards it. At each dynode 3-4 electrons are released for every incident electron, and with 6 to 14 dynodes the total gain, or electron amplification factor, will be in the range of ~10⁴-10⁷ when they reach the anode. Typical operating voltages are in the range of 500 to 3000 V. At the final dynode, sufficient electrons are available to produce a pulse of sufficient magnitude for further amplification. This pulse carries information about the energy of the original incident radiation. The number of such pulses per unit time also gives information about the intensity of the radiation.

See also:

Scintillation Counter

In general, spectroscopy is the science of studying the interaction between matter and radiated energy while spectrometry is the method used to acquire a quantitative measurement of the spectrum. Spectroscopy (scopy means observation) does not generate any results. It is the theoretical approach of science. Spectrometry (metry means measurement) is the practical application where the results are generated. It is the measurement of the intensity of the radiation using an electronic device. Often these terms are used interchangeably, but every spectrometry is not spectroscopy (e.g. mass spectrometry vs. mass spectroscopy).

Gamma Spectroscopy

In general, gamma spectroscopy is the study of the energy spectra of gamma ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Spectroscopes, or spectrometers, are sophisticated devices designed to measure the spectral power distribution of a source. The incident radiation generates a signal that allows to determine the energy of the incident particle.

Most radioactive sources produce gamma rays, which are of various energies and intensities. Gamma rays frequently accompany the emission of alpha and beta radiation. When these emissions are detected and analyzed with a spectroscopy system, a gamma-ray energy spectrum can be produced. Gamma rays from radioactive decay are in the energy range from a few keV to ~8 MeV, corresponding to the typical energy levels in nuclei with reasonably long lifetimes. As was written, they are produced by the decay of nuclei as they transition from a high energy state to a lower state. A detailed analysis of this spectrum is typically used to determine the identity and quantity of gamma emitters present in a sample, and is a vital tool in radiometric assay. The gamma spectrum is characteristic of the gamma-emitting nuclides contained in the source.

See also: Gamma Spectroscopy

X-Ray Spectroscopy

X-ray spectroscopy is a general term for several spectroscopic techniques for characterization of materials by using x-ray excitation. When an electron from the inner shell of an atom is excited by the energy of a photon, it moves to a higher energy level. Since the process leaves a vacancy in the electron energy level from which the electron came, the outer electrons of the atom cascade down to fill the lower atomic levels, and one or more characteristic X-rays are usually emitted. As a result, sharp intensity peaks appear in the spectrum at wavelengths that are a characteristic of the material from which the anode target is made. The frequencies of the characteristic X-rays can be predicted from the Bohr model. Analysis of the X-ray emission spectrum produces qualitative results about the elemental composition of the specimen.

Gamma Ray Spectrometer – Gamma Ray Spectroscope

As was written, the study and analysis of gamma ray spectra for scientific and technical use is called gamma spectroscopy, and gamma ray spectrometers are the instruments which observe and collect such data. A gamma ray spectrometer (GRS) is a sophisticated device for measuring the energy distribution of gamma radiation. For the measurement of gamma rays above several hundred keV, there are two detector categories of major importance, inorganic scintillators as NaI(Tl) and semiconductor detectors. In the previous articles, we described the gamma spectroscopy using scintillation detector, which consists of a suitable scintillator crystal, a photomultiplier tube, and a circuit for measuring the height of the pulses produced by the photomultiplier. The advantages of a scintillation counter are its efficiency (large size and high density) and the high precision and counting rates that are possible. Due to the high atomic number of iodine, a large number of all interactions will result in complete absorption of gamma-ray energy, so the photo fraction will be high.

But if a perfect energy resolution is required, we have to use germanium-based detector, such as the HPGe detector. Germanium-based semiconductor detectors are most commonly used where a very good energy resolution is required, especially for gamma spectroscopy, as well as x-ray spectroscopy. In gamma spectroscopy, germanium is preferred due to its atomic number being much higher than silicon and which increases the probability of gamma ray interaction. Moreover, germanium has lower average energy necessary to create an electron-hole pair, which is 3.6 eV for silicon and 2.9 eV for germanium. This also provides the latter a better resolution in energy. The FWHM (full width at half maximum) for germanium detectors is a function of energy. For a 1.3 MeV photon, the FWHM is 2.1 keV, which is very low.

See also:

Radiation Detection

The operation of scintillation counters and photomultiplier tubes is summarized in the following points:

• 

  Ionizing radiation enters the scintillator and interacts with the scintillator material. This cause electrons to be raised to an excited state.

  • For charged particles the track is the path of the particle itself.
  • For gamma rays (uncharged), their energy is converted to an energetic electron via either the photoelectric effect, Compton scattering or pair production.
• The excited atoms of the scintillator material de-excite and rapidly emit a photon in the visible (or near-visible) light range. The quantity is proportional to the energy deposited by the ionizing particle. The material is said to fluoresce.
• Three classes of phosphors are used:
  • inorganic crystals,
  • organic crystals,
  • plastic phosphors.
• The light created in the scintillator strikes the photocathode of a photomultiplier tube, releasing at most one photoelectron per photon.
• Using a voltage potential, this group of primary electrons is electrostatically accelerated and focused so that they strike the first dynode with enough energy to release additional electrons.
• These secondary electrons are attracted and strike a second dynode releasing more electrons. This process occurs in the photomultiplier tube.
• Each subsequent dynode impact releases further electrons, and so there is a current amplifying effect at each dynode stage. Each stage is at a higher potential than the previous to provide the accelerating field.
• Primary signal is multiplied and this amplification continues through 10 to 12 stages.
• At the final dynode, sufficient electrons are available to produce a pulse of sufficient magnitude for further amplification. This pulse carries information about the energy of the original incident radiation. The number of such pulses per unit time also gives information about the intensity of the radiation.

See also:

Scintillation Counters

In general, a phosphor is a substance that exhibits the phenomenon of luminescence. These materials are also used in scintillation detectors in various forms. The scintillator consists of a transparent crystal, usually a phosphor, plastic or organic liquid that fluoresces when struck by ionizing radiation. The scintillator must also be transparent to its own light emissions and it must have a short decay time because the transparence is important to a good light transmission to reach the electrode, and the short decay time allows fast response.

Inorganic Scintillation Phosphors

Inorganic scintillation phosphors are usually crystals grown in high temperature furnaces. They include lithium iodide (LiI), sodium iodide (NaI), cesium iodide (CsI), and zinc sulfide (ZnS). The most widely used scintillation material is NaI(Tl) (thallium-doped sodium iodide). The iodine provides most of the stopping power in sodium iodide (since it has a high Z = 53). These crystalline scintillators are characterized by high density, high atomic number, and pulse decay times of approximately 1 microsecond (~ 10^-6 sec). Scintillation in inorganic crystals is typically slower than in organic ones. They exhibit high efficiency for detection of gamma rays and are capable of handling high count rates. Inorganic crystals can be cut to small sizes and arranged in an array configuration so as to provide position sensitivity. This feature is widely used in medical imaging to detect X-rays or gamma rays. Inorganic scintillators are better at detecting gamma rays and X-rays. This is due to their high density and atomic number which gives a high electron density. A disadvantage of some inorganic crystals, e.g., NaI, is their hygroscopicity, a property which requires them to be housed in an airtight container to protect them from moisture.

See also:

Scintillation Counters

A scintillation counter or scintillation detector is a radiation detector which uses the effect known as scintillation. Scintillation is a flash of light produced in a transparent material by the passage of a particle (an electron, an alpha particle, an ion, or a high-energy photon). Scintillation occurs in the scintillator, which is a key part of a scintillation detector. In general, a scintillation detector consists of:

• Scintillator. The scintillator consists of a transparent crystal, usually a phosphor, plastic or organic liquid that fluoresces when struck by ionizing radiation.
• Photodetector. A sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal.

Phosphors – Scintillation Detectors

In general, a phosphor is a substance that exhibits the phenomenon of luminescence. These materials are also used in scintillation detectors in various forms. The scintillator consists of a transparent crystal, usually a phosphor, plastic or organic liquid that fluoresces when struck by ionizing radiation. The scintillator must also be transparent to its own light emissions and it must have a short decay time because the transparence is important to a good light transmission to reach the electrode, and the short decay time allows fast response.

Inorganic Scintillation Phosphors

Inorganic scintillation phosphors are usually crystals grown in high temperature furnaces. They include lithium iodide (LiI), sodium iodide (NaI), cesium iodide (CsI), and zinc sulfide (ZnS). The most widely used scintillation material is NaI(Tl) (thallium-doped sodium iodide). The iodine provides most of the stopping power in sodium iodide (since it has a high Z = 53). These crystalline scintillators are characterized by high density, high atomic number, and pulse decay times of approximately 1 microsecond (~ 10^-6 sec). Scintillation in inorganic crystals is typically slower than in organic ones. They exhibit high efficiency for detection of gamma rays and are capable of handling high count rates. Inorganic crystals can be cut to small sizes and arranged in an array configuration so as to provide position sensitivity. This feature is widely used in medical imaging to detect X-rays or gamma rays. Inorganic scintillators are better at detecting gamma rays and X-rays. This is due to their high density and atomic number which gives a high electron density. A disadvantage of some inorganic crystals, e.g., NaI, is their hygroscopicity, a property which requires them to be housed in an airtight container to protect them from moisture.

See also:

Scintillation Counters

A scintillation counter or scintillation detector is a radiation detector which uses the effect known as scintillation. Scintillation is a flash of light produced in a transparent material by the passage of a particle (an electron, an alpha particle, an ion, or a high-energy photon). Scintillation occurs in the scintillator, which is a key part of a scintillation detector. In general, a scintillation detector consists of:

• Scintillator. A scintillator generates photons in response to incident radiation.
• Photodetector. A sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal.

The basic principle of operation involves the radiation reacting with a scintillator, which produces a series of flashes of varying intensity. The intensity of the flashes is proportional to the energy of the radiation. This feature is very important. These counters are suited to measure the energy of  gamma radiation (gamma spectroscopy) and, therefore, can be used to identify gamma emitting isotopes.

Scintillation counters are widely used in radiation protection, assay of radioactive materials and physics research because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation. Hospitals all over the world have gamma cameras based on the scintillation effect and, therefore, they are also called scintillation cameras.

Advantages and disadvantages of scintillation counters are determined by the scintillator. The following features are not general for all scintillators.

Advantages of Scintillation Counters

• Efficiency. The advantages of a scintillation counter are its efficiency and the high precision and counting rates that are possible. These latter attributes are a consequence of the extremely short duration of the light flashes, from about 10^-9  (organic scintillators) to 10^-6 (inorganic scintillators) seconds.
• Spectroscopy. The intensity of the flashes and the amplitude of the output voltage pulse are proportional to the energy of the radiation. Therefore, scintillation counters can be used to determine the energy, as well as the number, of the exciting particles (or gamma photons). For gamma spectrometry, the most common detectors include sodium iodide (NaI) scintillation counters and high-purity germanium detectors. The NaI(Tl) scintillator has a higher energy resolution than a proportional counter, allowing for more accurate energy determinations. On the other hand, if a perfect energy resolution is required, we have to use germanium-based detector, such as the HPGe detector.

Disadvantages of Scintillation Counters

• Hygroscopicity. A disadvantage of some inorganic crystals, e.g., NaI, is their hygroscopicity, a property which requires them to be housed in an airtight container to protect them from moisture.
• NaI(Tl) has no beta or alpha response and poor low energy gamma response.
• Liquid scintillators are relatively cumbersome.

See also:

Scintillation Counters

A scintillation counter or scintillation detector is a radiation detector which uses the effect known as scintillation. Scintillation is a flash of light produced in a transparent material by the passage of a particle (an electron, an alpha particle, an ion, or a high-energy photon). Scintillation occurs in the scintillator, which is a key part of a scintillation detector. In general, a scintillation detector consists of:

• Scintillator. A scintillator generates photons in response to incident radiation.
• Photodetector. A sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal.

Scintillation counters are widely used in radiation protection, assay of radioactive materials and physics research because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation. Hospitals all over the world have gamma cameras based on the scintillation effect and, therefore, they are also called scintillation cameras.

The advantages of a scintillation counter are its efficiency and the high precision and counting rates that are possible. These latter attributes are a consequence of the extremely short duration of the light flashes, from about 10^-9  (organic scintillators) to 10^-6 (inorganic scintillators) seconds. The intensity of the flashes and the amplitude of the output voltage pulse are proportional to the energy of the radiation. Therefore, scintillation counters can be used to determine the energy, as well as the number, of the exciting particles (or gamma photons). For gamma spectrometry, the most common detectors include sodium iodide (NaI) scintillation counters and high-purity germanium detectors.

Applications of Scintillation Counters

Scintillation counters are used to measure radiation in a variety of applications including hand held radiation survey meters, personnel and environmental monitoring for radioactive contamination, medical imaging, radiometric assay, nuclear security and nuclear plant safety. They are widely used because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation.

Scintillation counters can be used to detect alpha, beta, gamma radiation. They can be used also for detection of neutrons. For these purposes, different scintillators are used:

• 

  Alpha Particles and Heavy Ions. Due to the very high ionizing power of heavy ions, scintillation counters are usually not ideal for the detection of heavy ions. For equal energies, a proton will produce 1/4 to 1/2 the light of an electron, while alpha particles will produce only about 1/10 the light. Where needed, inorganic crystals, e.g. CsI(Tl), ZnS(Ag) (typically used in thin sheets as α-particle monitors), should be preferred to organic materials. Pure CsI is a fast and dense scintillating material with relatively low light yield that increases significantly with cooling. The drawbacks of CsI are a high temperature gradient and a slight hygroscopicity.

• Beta Particles. For detection of beta particles, organic scintillators can be used. Pure organic crystals include crystals of anthracene, stilbene and naphthalene. The decay time of this type of phosphor is approximately 10 nanoseconds. This type of crystal is frequently used in the detection of beta particles. Organic scintillators, having a lower Z than inorganic crystals, are best suited for the detection of low-energy (< 10 MeV) beta particles.
• Gamma Rays. High-Z materials are best suited as scintillators for the detection of gamma rays. The most widely used scintillation material is NaI(Tl) (thallium-doped sodium iodide). The iodine provides most of the stopping power in sodium iodide (since it has a high Z = 53). These crystalline scintillators are characterized by high density, high atomic number, and pulse decay times of approximately 1 microsecond (~ 10^-6 sec). Scintillation in inorganic crystals is typically slower than in organic ones. They exhibit high efficiency for detection of gamma rays and are capable of handling high count rates. Inorganic crystals can be cut to small sizes and arranged in an array configuration so as to provide position sensitivity. This feature is widely used in medical imaging to detect X-rays or gamma rays. Inorganic scintillators are better at detecting gamma rays and X-rays. This is due to their high density and atomic number which gives a high electron density.
• Neutrons. Since the neutrons are electrically neutral particles, they are mainly subject to strong nuclear forces but not to electric forces. Therefore neutrons are not directly ionizing and they have usually to be converted into charged particles before they can be detected. Generally every type of neutron detector must be equipped with converter (to convert neutron radiation to common detectable radiation) and one of the conventional radiation detectors (scintillation detector, gaseous detector, semiconductor detector, etc.).  Fast neutrons (>0.5 MeV) primarily rely on the recoil proton in (n,p) reactions. Materials rich in hydrogen, for example plastic scintillators, are therefore best suited for their detection. Thermal neutrons rely on nuclear reactions such as the (n,γ) or (n,α) reactions, to produce ionization. Materials such as LiI(Eu) or glass silicates are therefore particularly well-suited for the detection of thermal neutrons.

See also:

Scintillation Counters

A scintillation counter or scintillation detector is a radiation detector which uses the effect known as scintillation. Scintillation is a flash of light produced in a transparent material by the passage of a particle (an electron, an alpha particle, an ion, or a high-energy photon). Scintillation occurs in the scintillator, which is a key part of a scintillation detector. In general, a scintillation detector consists of:

• Scintillator. A scintillator generates photons in response to incident radiation.
• Photodetector. A sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal.

Detection of Neutrons using Scintillation Counter

Scintillation counters are used to measure radiation in a variety of applications including hand held radiation survey meters, personnel and environmental monitoring for radioactive contamination, medical imaging, radiometric assay, nuclear security and nuclear plant safety. They are widely used because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation.

Scintillation counters can be used to detect alpha, beta, gamma radiation. They can be used also for detection of neutrons. For this purpose, different scintillators are used:

• Neutrons. Since the neutrons are electrically neutral particles, they are mainly subject to strong nuclear forces but not to electric forces. Therefore neutrons are not directly ionizing and they have usually to be converted into charged particles before they can be detected. Generally every type of neutron detector must be equipped with converter (to convert neutron radiation to common detectable radiation) and one of the conventional radiation detectors (scintillation detector, gaseous detector, semiconductor detector, etc.).  Fast neutrons (>0.5 MeV) primarily rely on the recoil proton in (n,p) reactions. Materials rich in hydrogen, for example plastic scintillators, are therefore best suited for their detection. Thermal neutrons rely on nuclear reactions such as the (n,γ) or (n,α) reactions, to produce ionization. Materials such as LiI(Eu) or glass silicates are therefore particularly well-suited for the detection of thermal neutrons.

See also:

Scintillation Counters

A scintillation counter or scintillation detector is a radiation detector which uses the effect known as scintillation. Scintillation is a flash of light produced in a transparent material by the passage of a particle (an electron, an alpha particle, an ion, or a high-energy photon). Scintillation occurs in the scintillator, which is a key part of a scintillation detector. In general, a scintillation detector consists of:

• Scintillator. A scintillator generates photons in response to incident radiation.
• Photodetector. A sensitive photodetector (usually a photomultiplier tube (PMT), a charge-coupled device (CCD) camera, or a photodiode), which converts the light to an electrical signal and electronics to process this signal.

Scintillation counters are widely used in radiation protection, assay of radioactive materials and physics research because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation. Hospitals all over the world have gamma cameras based on the scintillation effect and, therefore, they are also called scintillation cameras.

The advantages of a scintillation counter are its efficiency and the high precision and counting rates that are possible. These latter attributes are a consequence of the extremely short duration of the light flashes, from about 10^-9  (organic scintillators) to 10^-6 (inorganic scintillators) seconds. The intensity of the flashes and the amplitude of the output voltage pulse are proportional to the energy of the radiation. Therefore, scintillation counters can be used to determine the energy, as well as the number, of the exciting particles (or gamma photons). For gamma spectrometry, the most common detectors include sodium iodide (NaI) scintillation counters and high-purity germanium detectors.

Detection of Alpha, Beta and Gamma Radiation using Scintillation Counter

Scintillation counters are used to measure radiation in a variety of applications including hand held radiation survey meters, personnel and environmental monitoring for radioactive contamination, medical imaging, radiometric assay, nuclear security and nuclear plant safety. They are widely used because they can be made inexpensively yet with good efficiency, and can measure both the intensity and the energy of incident radiation.

Scintillation counters can be used to detect alpha, beta, gamma radiation. They can be used also for detection of neutrons. For these purposes, different scintillators are used:

• Alpha Particles and Heavy Ions. Due to the very high ionizing power of heavy ions, scintillation counters are usually not ideal for the detection of heavy ions. For equal energies, a proton will produce 1/4 to 1/2 the light of an electron, while alpha particles will produce only about 1/10 the light. Where needed, inorganic crystals, e.g. CsI(Tl), ZnS(Ag) (typically used in thin sheets as α-particle monitors), should be preferred to organic materials. Pure CsI is a fast and dense scintillating material with relatively low light yield that increases significantly with cooling. The drawbacks of CsI are a high temperature gradient and a slight hygroscopicity.
• Beta Particles. For detection of beta particles, organic scintillators can be used. Pure organic crystals include crystals of anthracene, stilbene and naphthalene. The decay time of this type of phosphor is approximately 10 nanoseconds. This type of crystal is frequently used in the detection of beta particles. Organic scintillators, having a lower Z than inorganic crystals, are best suited for the detection of low-energy (< 10 MeV) beta particles.
• Gamma Rays. High-Z materials are best suited as scintillators for the detection of gamma rays. The most widely used scintillation material is NaI(Tl) (thallium-doped sodium iodide). The iodine provides most of the stopping power in sodium iodide (since it has a high Z = 53). These crystalline scintillators are characterized by high density, high atomic number, and pulse decay times of approximately 1 microsecond (~ 10^-6 sec). Scintillation in inorganic crystals is typically slower than in organic ones. They exhibit high efficiency for detection of gamma rays and are capable of handling high count rates. Inorganic crystals can be cut to small sizes and arranged in an array configuration so as to provide position sensitivity. This feature is widely used in medical imaging to detect X-rays or gamma rays. Inorganic scintillators are better at detecting gamma rays and X-rays. This is due to their high density and atomic number which gives a high electron density.
• Neutrons. Since the neutrons are electrically neutral particles, they are mainly subject to strong nuclear forces but not to electric forces. Therefore neutrons are not directly ionizing and they have usually to be converted into charged particles before they can be detected. Generally every type of neutron detector must be equipped with converter (to convert neutron radiation to common detectable radiation) and one of the conventional radiation detectors (scintillation detector, gaseous detector, semiconductor detector, etc.).  Fast neutrons (>0.5 MeV) primarily rely on the recoil proton in (n,p) reactions. Materials rich in hydrogen, for example plastic scintillators, are therefore best suited for their detection. Thermal neutrons rely on nuclear reactions such as the (n,γ) or (n,α) reactions, to produce ionization. Materials such as LiI(Eu) or glass silicates are therefore particularly well-suited for the detection of thermal neutrons.

See also:

Scintillation Counters

The sensitivity of a photocathode is usually quoted in terms of the quantum efficiency. In general, the term quantum efficiency (QE) may apply to incident photon to converted electron (IPCE) ratio of a photosensitive device. The quantum efficiency of the photocathode is defined as the probability for the conversion of incident photons to an electrical signal and is defined as:

The quantum efficiency of any photosensitive device is a strong function of wavelength of the incident light, and an effort is made to match the spectral response of the photocathode to the emission spectrum of the scintillator in use. In the photomultiplier tube the quantum efficiency is limited to 20-30%, but an average quantum efficiency over the emission spectrum of a typical scintillator is about 15-20%.

The standard for quotation is the number of photoelectrons per keV energy loss by fast electrons in a NaI(Tl) scintillator. For the peak quantum efficiency, about 8 ~ 10 photoelectrons are produced per each keV energy loss. Therefore, the average energy loss required to create a single photoelectron is ~ 100 eV, which is much bigger than the values in gas-filled detectors or semiconductor detectors.

The PMT has been the main choice for photon detection ever since due to the fact that they have high quantum efficiency and high amplification. Lately however semiconductors have begun to compete with the PMT, the photodiode for example which has higher quantum efficiency in the visible range and above, lower power consumption and smaller size. The quantum efficiency for the photodiode is high (60-80%) compared to the PMT (20-30%) which gives a higher energy resolution.

See also:

Scintillation Counters