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What is Gamma Spectroscopy – Definition

Gamma spectroscopy is the study of the energy spectra of gamma ray sources, such as in the nuclear industry and geochemical investigation. The gamma spectrum is characteristic of the gamma-emitting nuclides contained in the source. Radiation Dosimetry

In general, spectroscopy is the science of studying the interaction between matter and radiated energy while spectrometry is the method used to acquire a quantitative measurement of the spectrum. Spectroscopy (scopy means observation) does not generate any results. It is the theoretical approach of science. Spectrometry (metry means measurement) is the practical application where the results are generated. It is the measurement of the intensity of the radiation using an electronic device. Often these terms are used interchangeably, but every spectrometry is not spectroscopy (e.g. mass spectrometry vs. mass spectroscopy).

Distinction between X-rays and gamma rays

The distinction between X-rays and gamma rays is not so simple and has changed in recent decades. Yes, X-rays are being said to have lower energies, but this is not the rule and the main difference. According to the currently valid definition, X-rays are emitted by electrons outside the nucleus, while gamma rays are emitted by the nucleus.

Gamma Spectroscopy

Source: wikipedia.org License: Public Domain

In general, gamma spectroscopy is the study of the energy spectra of gamma ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Spectroscopes, or spectrometers, are sophisticated devices designed to measure the spectral power distribution of a source. The incident radiation generates a signal that allows to determine the energy of the incident particle.

Most radioactive sources produce gamma rays, which are of various energies and intensities. Gamma rays frequently accompany the emission of alpha and beta radiation. When these emissions are detected and analyzed with a spectroscopy system, a gamma-ray energy spectrum can be produced. Gamma rays from radioactive decay are in the energy range from a few keV to ~8 MeV, corresponding to the typical energy levels in nuclei with reasonably long lifetimes. As was written, they are produced by the decay of nuclei as they transition from a high energy state to a lower state. A detailed analysis of this spectrum is typically used to determine the identity and quantity of gamma emitters present in a sample, and is a vital tool in radiometric assay. The gamma spectrum is characteristic of the gamma-emitting nuclides contained in the source.

X-Ray Spectroscopy

X-ray spectroscopy is a general term for several spectroscopic techniques for characterization of materials by using x-ray excitation. When an electron from the inner shell of an atom is excited by the energy of a photon, it moves to a higher energy level. Since the process leaves a vacancy in the electron energy level from which the electron came, the outer electrons of the atom cascade down to fill the lower atomic levels, and one or more characteristic X-rays are usually emitted. As a result, sharp intensity peaks appear in the spectrum at wavelengths that are a characteristic of the material from which the anode target is made. The frequencies of the characteristic X-rays can be predicted from the Bohr model. Analysis of the X-ray emission spectrum produces qualitative results about the elemental composition of the specimen.

Gamma Ray Spectrometer – Gamma Ray Spectroscope

As was written, the study and analysis of gamma ray spectra for scientific and technical use is called gamma spectroscopy, and gamma ray spectrometers are the instruments which observe and collect such data. A gamma ray spectrometer (GRS) is a sophisticated device for measuring the energy distribution of gamma radiation. For the measurement of gamma rays above several hundred keV, there are two detector categories of major importance, inorganic scintillators as NaI(Tl) and semiconductor detectors. In the previous articles, we described the gamma spectroscopy using scintillation detector, which consists of a suitable scintillator crystal, a photomultiplier tube, and a circuit for measuring the height of the pulses produced by the photomultiplier. The advantages of a scintillation counter are its efficiency (large size and high density) and the high precision and counting rates that are possible. Due to the high atomic number of iodine, a large number of all interactions will result in complete absorption of gamma-ray energy, so the photo fraction will be high.

HPGe Detector - Germanium
HPGe detector with LN2 cryostat Source: canberra.com

But if a perfect energy resolution is required, we have to use germanium-based detector, such as the HPGe detector. Germanium-based semiconductor detectors are most commonly used where a very good energy resolution is required, especially for gamma spectroscopy, as well as x-ray spectroscopy. In gamma spectroscopy, germanium is preferred due to its atomic number being much higher than silicon and which increases the probability of gamma ray interaction. Moreover, germanium has lower average energy necessary to create an electron-hole pair, which is 3.6 eV for silicon and 2.9 eV for germanium. This also provides the latter a better resolution in energy. The FWHM (full width at half maximum) for germanium detectors is a function of energy. For a 1.3 MeV photon, the FWHM is 2.1 keV, which is very low.

Gamma Spectrum Structure – The Cobalt-60 Spectrum

Analysis of gamma spectra is very interesting, since it has a structure and workers must distinguish between true pulses to be analyzed and accompanying pulses from different sources of radiation. We will show the structure of the gamma spectrum on the example of cobalt-60 measured by NaI(Tl) scintillation detector and by the HPGe detector. The HPGe detector allows the separation of many closely spaced gamma lines, which is very beneficial for measuring multi-gamma emitting radioactive sources.

cobalt-60 decay scheme

Cobalt-60  is an artificial radioactive isotope of cobalt with a half-life of 5.2747 years. It is synthetically produced by neutron activation of cobalt-59 in nuclear reactors. Cobalt-60 is a common calibration source found in many laboratories. The gamma spectrum has two significant peaks, one at 1173.2 keV and another at 1332.5 keV. Good scintillation detectors should have adequate resolution to separate the two peaks. For HPGe detectors, these peaks are perfectly separated.

As can be seen from the figure, there are two gamma ray photopeaks. Both detectors also show response at the lower energies, caused by Compton scattering, two smaller escape peaks at energies 0.511 and 1.022 MeV below the photopeak for the creation of electron-positron pairs when one or both annihilation photons escape, and a backscatter peak. Higher energies can be measured when two or more photons strike the detector almost simultaneously, appearing as sum peaks with energies up to the value of two or more photopeaks added.

HPGe Detector spectrum
Figure: Caption: Comparison of NaI(Tl) and HPGe spectra for cobalt-60. Source: Radioisotopes and Radiation Methodology I, II. Soo Hyun Byun, Lecture Notes. McMaster University, Canada.

 

General structure of gamma rays spectrum usually has the following principle features:

  • Photopeaks are full energy peaks, that are created, when γ-ray transfers its full energy (hω −Ebinding) into the sensitive material (scintillation crystal or germanium crystal). Than a single delta function should be observed in the spectrum.The cobalt-60 spectrum contains two photopeaks, one at 1173.2 keV and another at 1332.5 keV.
  • Compton Continuum. In the crystal, a gamma ray undergoes a number of interactions, but for intermediate energies compton scattering dominates. In compton scattering, the incident gamma ray photon is deflected through an angle Θ with respect to its original direction. The photon transfers a portion of its energy to the recoil electron. The energy transferred to the recoil electron can vary from zero to a large fraction (maximum E) of the incident gamma ray energy, because all angles of scattering are possible.  The size of the scintillation crystal changes the ratio between photopeak and Compton continuum. For an infinitely large spherical detector centered around a source no photons would be able to escape and only a photopeak would be seen on the spectrum. For very small detectors the chance for a photon to leave after Compton scattering is high and the Compton continuum would be large compared to the photopeak.
  • Compton Edge.  The Compton edge is a feature of the spectrograph that results from the Compton scattering in the scintillator or detector. This feature is due to photons that undergo Compton scattering with a scattering angle of 180° and then escape the detector. When a gamma ray scatters off the detector and escapes, only a fraction of its initial energy can be deposited in the sensitive layer of the detector. It depends on the scattering angle of the photon, how much energy will be deposited in the detector. This leads to a spectrum of energies. The Compton edge energy corresponds to full backscattered photon.  The counts between Compton edge and the photopeaks are caused by multiple Compton scattering events, where scattered gamma photon exits the sensitive material.

Sometimes the structure of gamma rays spectrum has the following secondary features:

  • Compton edge of 60Co on gamma spectrometer Na(Tl).
    Compton edge of 60Co on gamma spectrometer Na(Tl).

    Backscatter Peak. A Compton backscatter peak is found when γ-rays enter the material around the detector and are scattered back into the detector. Gamma photon can interact by Compton mechanism in shield or surrounding materials and is backscattered out of a material into sensitive volume. Maximum photon energy in this interaction is ~200 keV regardless of initial photon energy. This results in a secondary peak at -200 keV.

  • X-ray Peaks. When the gamma rays undergoes photoelectric effect in surrounding materials (for example lead shield) the outgoing X-ray can be captured again by the detector. This gives an characteristic X-ray peak with an energy depending on the material it came from. In case of lead the characteristic X-ray energies is in the 72-84 keV range. Photoelectric absorption by K-shell electron in lead of shielding, resulting in a K-shell vacancy. The K -> L transition for lead = 72 keV. If this characteristic x-ray is absorbed in the crystal then a secondary peak at 72 keV is observed.
  • Coincidence Peak. Simultaneous absorption of two gamma photons in crystal, resulting in a peak higher in energy than the photopeak. The gamma photons may result from serial isomeric transitions (e.g. 2 keV plus 1332.5 keV in case of cobalt-60) or simultaneous decays in separate radionuclides (e.g. 2 x 1173.2 keV in case of cobalt-60).
  • Annihilation Peak. For high energy gamma rays (greater than 1.02 MeV), electron-positron pair production is a possible interaction. But a positron may then annihilate in the detector or in the surrounding material. If both 0.51 MeV annihilation photons are absorbed in the crystal, a secondary peak 1.02 MeV below the photopeak can be found. If one annihilation photon is absorbed and the second exits the crystal, then 0.51 MeV is removed from the photopeak, resulting in a secondary peak 0.51 MeV below the photopeak. The probability is greater that one annihilation photon will be absorbed.
References:

Radiation Protection:

  1. Knoll, Glenn F., Radiation Detection and Measurement 4th Edition, Wiley, 8/2010. ISBN-13: 978-0470131480.
  2. Stabin, Michael G., Radiation Protection and Dosimetry: An Introduction to Health Physics, Springer, 10/2010. ISBN-13: 978-1441923912.
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Nuclear and Reactor Physics:

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  9. Paul Reuss, Neutron Physics. EDP Sciences, 2008. ISBN: 978-2759800414.

See also:

Radiation Detection

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